97040
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97040
Fluka
(±)-Z-α-Phosphonoglycine trimethyl ester
purum, ≥97.0% (HPLC)
| Synonym: | (±)-Trimethyl Z-α-phosphonoglycinate, (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate |
| CAS Number: | 88568-95-0 |
| Linear Formula: | (CH3O)2P(O)CH(NHCO2CH2C6H5)CO2CH3 |
| Molecular Weight: | 331.26 |
| Beilstein Registry Number: | 5764460 |
| MDL number: | MFCD00043304 |
| PubChem Substance ID: | 24890381 |
Description
| Application | Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids. |
Properties
| grade | purum |
| assay | ≥97.0% (HPLC) |
| mp | 77-80 °C(lit.) |
| 78-80 °C |
Safety
| Safety Statements | 22-24/25 |
| WGK Germany | 3 |
Related Products
| Replaced by | 376353, Z-α-Phosphonoglycine trimethyl ester |
References
| reference | U. Schmidt Synthesis, 53, (1984) |
| A. Lieberknecht, H. Griesser Tetrahedron Lett. 28, 42750, (1987) | |
| P.G. Ciattini Synthesis, 140, (1988) | |
| U. Schmidt Synthesis, 49, (1991) | |
| FT-NMR 1 (2), 1692:C / RegBook 1 (2), 2291:I / Structure Index 1, 359:B:1 |
